Traceable Knowledge Graph Reasoning Enables LLM-Assisted Decision Support for Industrial VOCs in the Steel Industry
Authors: Changqing Su, Yu Ding, Zuhong Lin, Hongyu Liu, Xi He, Zheng Zeng, Liqing Li
Organizations: Hunan Key Laboratory of Carbon Neutrality and Intelligent Energy, School of New Energy and Environment, Hunan University of Technology and Business, Changsha 410205, P.R. China · Aerospace Kaitian Environmental Technology Co., Ltd., Changsha 410315, P.R. China · School of Energy Science and Engineering, Central South University, Changsha2026 410083, P.R. China
Key knowledge for steel-industry volatile organic compounds (VOCs) governance is scattered across unstructured scientific literature, making it difficult to integrate process, pollutant, and control-technology evidence and increasing the risk of hallucination when general large language models (LLMs) answer low-frequency industrial questions. Here we developed Chat-ISV, a knowledge graph (KG) enhanced multi-agent Q&A system that parses a curated steel-industry VOCs literature corpus, constructs a Neo4j KG with 27180 nodes and 81779 semantic edges, and combines prompt-constrained extraction, chunk-centered topology optimization, multi-agent routing, source-backtracking retrieval, local literature retrieval, open-domain knowledge access, and interactive subgraph visualization. Benchmark tests and 400 expert blind evaluations showed that topology optimization reduced isolated nodes from 57% to 4.08% and that Chat-ISV achieved high factual reliability, with 96.93% precision, 72.63% recall, an F1-score of 0.830, and a mean score of 1.69/2.00. By converting fragmented environmental-engineering literature into traceable, queryable, and decision-support-oriented knowledge, Chat-ISV establishes a scalable environmental-informatics paradigm for reliable LLM deployment and intelligent pollution-control decision support in specialized industrial domains.
LLM-based agents for industrial asset operations show limited accuracy when reasoning over flat document stores. AssetOpsBench (KDD 2026) establishes that GPT-4 agents achieve 65% on 139 industrial maintenance scenarios, and compares LLM orchestration paradigms (Agent-As-Tool vs. Plan-Execute) on a fixed data layer. We ask the orthogonal question: how much does the data model behind the tools matter? We treat a typed knowledge graph as a grounding substrate and route each question by how it is best answered: (i) LLM-generated Cypher for structured retrieval, which lifts the same GPT-4 model from 65% to 82-83%; (ii) native graph and optimization primitives, with no LLM, reaching 99% on graph-answerable scenarios; and (iii) generation-augmented knowledge (GAK) for answers absent from the data -- the engine's agent materializes the missing facts as provenance-tagged graph nodes, then answers. A recurring theme is inverted LLM usage: we constrain the LLM to query generation or one-shot enrichment from a typed schema and let the graph execute deterministically. On the 88 real AssetOpsBench failure-mode scenarios the benchmark itself flags non-deterministic -- ten equipment types absent from the graph -- GAK lifts answerability from zero to 100% of equipment types and answers 81.8% of scenarios, every materialized fact tagged source:LLM-derived for auditability. We also contribute 40 graph-native scenarios. For structured operational domains the data layer -- not the LLM orchestration -- is the primary lever, and a typed knowledge graph serves as a grounding substrate between raw industrial data and LLM reasoning.
Retrieval-Augmented Generation (RAG) fails systematically on queries requiring structural reasoning over interconnected entities. We compare eight retrieval architectures for aerospace supply chain intelligence, progressing from text retrieval through graph traversal to graph computation. Using a 46-node knowledge graph with 64 typed edges, we evaluate 23 queries across 10 intent categories and demonstrate that five query classes are structurally unreachable for vector retrieval. Our central finding is the operator vocabulary thesis: the barrier to LLM-based graph reasoning is not model intelligence but the computational operators available as tools. An LLM Query Planner with 9 typed traversal primitives outperforms bespoke handlers (F1 = 0.632 vs. 0.472) while generalizing to unseen queries. Adding 6 graph computation tools, the LLM selectively adopts them for exactly the query categories where traversal fails. We also identify a measurement gap: entity-level F1 systematically underscores structural queries where comprehensive answers are correct.
Knowledge graphs (KGs) are often automatically constructed from large-scale corpora, but they inevitably contain factual errors due to noisy sources and extraction failures, and verifying them reliably at industrial scale remains a critical challenge. To address this, we propose AgentKGV, the Agentic LLM-RAG framework for KG fact Verification, that integrates dynamic routing and iterative query rewriting, which handles surface-form mismatch in document-level retrieval. To make this framework more accurate and cost-efficient for industrial deployment, we further introduce a two-stage training strategy: turn-level distillation-based SFT that transfers reasoning ability from a large teacher model into a small model for stable query rewriting and reasoning, and trajectory-level GRPO that optimizes the search policy to reduce unnecessary retrieval at scale. On the long-tail-predicate split of the open-domain T-REx benchmark, our framework improves macro-F1 over single-turn RAG by 5.5 %p, and two-stage training does it further by 9.4 %p. GRPO also cuts the average number of search calls from 3.24 to 1.63 without lowering accuracy.