Physics-informed distribution of relaxation times estimation and latent-space condition monitoring of solid oxide fuel and electrolysis cells from electrochemical impedance spectroscopy

This paper introduces AutoREC, an open-source Python platform for developing, training, and evaluating reinforcement learning (RL) agents that automatically generate equivalent circuit models (ECMs) from electrochemical impedance spectroscopy (EIS) data. Although ECMs are widely used to interpret EIS measurements, their identification typically relies on manual trial-and-error, requiring domain expertise and limiting scalability, particularly in autonomous experimental pipelines such as self-driving laboratories. In AutoREC, ECM generation is formulated as a Markov decision process in which an RL agent sequentially modifies a circuit topology based on the current state, available actions, and feedback from the resulting model. The platform supports an end-to-end workflow encompassing EIS preprocessing with selectable impedance representations, agent setup and training, ECM generation for new measurements, and visualization-based evaluation and analysis of agent decision-making. AutoREC implements a configurable Double Deep Q-Network (DDQN) agent with prioritized experience replay and a dedicated dead-loop mitigation strategy for navigating the complex circuit-generation action space efficiently. To demonstrate the platform, we trained and evaluated a representative agent on synthetic EIS datasets and applied it to previously unseen experimental spectra from battery, corrosion, oxygen evolution reaction, and CO$_2$ reduction systems. These case studies illustrate the end-to-end capabilities of AutoREC while revealing challenges associated with experimental complexity and limited training-data coverage. The demonstrated agent serves as a reference implementation; AutoREC provides an extensible foundation through which users can develop and evaluate agents tailored to their specific electrochemical systems and research objectives.

This study proposes a bound-constrained sparse representation (BC-SR) framework for electrical impedance tomography (EIT), aimed at improving conductivity estimation without explicit regularization. BC-SR adopts a representation-driven strategy, generating conductivity from low-dimensional latent variables via an implicit composite parameterization. Structural priors are embedded using a truncated graph-Laplacian basis, while a bound-preserving nonlinear mapping enforces admissible conductivity ranges and improves conditioning through implicit gradient modulation. The approach ensures robust convergence, even under noisy or incomplete data. Extensive validation on 2D/3D simulations, tank experiments, and in-vivo lung data shows that BC-SR improves physical consistency and structural fidelity, offering enhanced robustness compared to traditional methods. Additionally, BC-SR enables 3D time-difference EIT reconstruction, offering improved spatial resolution and a more coherent representation of 3D conductivity distributions, particularly for in-vivo lung data. This suggests potential for improved performance in EIT, particularly in clinical applications for respiratory monitoring.

Accurate remaining discharge time (RDT) prediction is challenging in real-world battery applications because future load profiles are unknown and highly dynamic. To address the uncertainty of continuous RDT regression, this paper introduces Relative Discharge Stage (RDS), a battery-management indicator that represents the remaining discharge condition using five interpretable classes: Normal, Good, Moderate, Low, and Recharge Required. Unlike state of charge (SOC), which reflects the current charge level, RDS characterizes the remaining discharge process without requiring future-current information during inference. A physics-informed RDS classification framework is proposed, combining SOC estimation with lightweight temporal learning. The SOC-estimation component includes second-order ECM state and terminal-voltage prediction, hysteresis and OCV temperature correction, core-temperature estimation, and AEKF state correction, supported by OCV evaluation, online STC-ECM parameter adaptation, and pretrained neural residual-voltage correction. The measured current, terminal voltage, surface temperature, and estimated SOC are arranged into a sliding observation window and processed by a lightweight temporal convolutional network. Experiments on two public lithium-ion battery datasets demonstrate robust RDS classification, with accuracy exceeding 80% under varying load and thermal conditions.