The curvature exponent α in hk∝σkα -- governing how Hessian eigenvalues scale with gradient singular values -- varies systematically across layer types (α≈2 for convolutions, ≈1 for transformer attention, <1 for MLP up-projections). Why? We prove the Spectral Alignment Decomposition: α=2+dlogΦk/dlogσk, where Φk measures alignment between Kronecker factor eigenbases and gradient singular directions. This reduces "why does α vary?" to a geometric question we answer for LayerNorm, residual connections, and softmax heads. The decomposition implies a spectral transfer identity s=αγ linking curvature exponent, effective gradient rank-decay γ, and Hessian decay exponent s. The identity is algebraic; its empirical content is that α and γ, fit on independent data (HVPs vs. SVD), recover s to ~2% median error across 93 layers, five architectures, and three datasets -- with no free parameters. A zeta-function bound on participation ratio shows curvature concentrates onto effectively one direction per layer. As a proof of concept, we derive the architecture-adaptive preconditioner T(σ;α) and show that Spectral Newton -- implementing T in the gradient singular basis -- outperforms AdamW on vision benchmarks where α≈2.