Poisson subsampling is the default sampling scheme in differentially private machine learning, largely because its unstructured randomness yields tractable privacy amplification analyses. Yet this same randomness introduces substantial participation variance: each sample appears in very different numbers of training iterations. In this work, we show that this variance is not merely a practical artifact to be tolerated, but a fundamental source of suboptimal privacy amplification. We prove that Balanced Iteration Subsampling (BIS), a structured scheme in which each sample participates in exactly a fixed number of iterations, achieves stronger privacy amplification than Poisson subsampling and is optimal at both extremes of the noise spectrum (
σ→0 and
σ→∞). Our analysis reveals that the privacy-noise tradeoff is governed not by maximizing randomness, but by eliminating participation variance while preserving uniform marginal participation across iterations. To translate this asymptotic theory into finite-noise guarantees, we introduce a practical near-exact Monte Carlo accountant for BIS, which removes the analytical slack of existing RDP and composition-based PLD analyses. Evaluations across more than 60 practical DP-SGD configurations show that BIS consistently outperforms Poisson subsampling in the low-noise regimes most relevant for high-utility private training, reducing the required noise multiplier by up to
9.6%. These results overturn the common intuition that more sampling randomness necessarily yields stronger privacy amplification: in DP-SGD, structured participation can be both more practical and more private. Our implementation is available at https://github.com/dong-xin-ao-andy/bis-mc-accountant.