A Statistical and Machine Learning Framework for Operational Threshold Detection and Deployable Dispatch Controller Development in Hydrogen Multi-Energy Systems

Hydrogen supply chains are expected to play a central role in future low-carbon energy systems by enabling renewable energy integration, long-duration storage, and decarbonization of industrial and transportation sectors. However, their operation is challenged by renewable generation variability, electricity price fluctuations, uncertain hydrogen demand, and engineering constraints associated with electrolyzers, energy storage, and grid interaction. As hydrogen infrastructure expands toward commercial deployment, operational strategies must balance economic performance, reliability, and sustainability under dynamic and uncertain conditions. This paper investigates and compares four control approaches for a renewable-powered hydrogen supply chain: a rule-based controller (RBC), model predictive control (MPC), reinforcement learning without forecasts (RL-NF), and reinforcement learning with forecast-augmented observations (RL-F). All methods are evaluated within a unified, physically realistic framework incorporating electrolyzer minimum-load and ramp-rate constraints, battery and hydrogen storage dynamics, grid import limits, and consistent economic assumptions, enabling a fair comparison under identical operating conditions. Simulation results show that MPC achieves the highest economic performance by exploiting short-term forecasts to coordinate storage, reduce grid dependence, and improve efficiency. RL-NF demonstrates robust and competitive performance without future information, highlighting the capability of learning-based methods to discover effective policies from experience. RL-F does not consistently outperform its no-forecast counterpart, suggesting that forecast uncertainty and increased state complexity can limit forecast-augmented learning. The results provide guidance for selecting operational control strategies in future hydrogen energy systems.

Green hydrogen plays an essential role in decarbonization, with capacity projected to scale to 560 GW by 2030 (vs. 1.39 GW in 2023) in net-zero settings. Proton exchange membrane (PEM) electrolysis is one of the most promising technology routes to green hydrogen production, and real-time system health monitoring of PEM electrolyzers is essential for their scalable deployment. In lab settings, performance degradation can be characterized through electrochemical testing protocols by periodic pauses of normal operation. Such interruption is not practical for full-scale stack deployments, limiting system operators' ability to make real-time assessments of state-of-health (SoH). We present a machine learning (ML) framework that performs virtual electrochemical characterization during normal operation. The method uses an encoder-decoder transformer, conditioned on operational data, to reconstruct characterization outputs, focusing here on polarization curves. Inspired by patch-based sequence tokenization, we segment the inputs into patches and encode them to form meaningful tokens, which substantially improves learning efficiency. Across four longitudinal runs, lasting up to 478 hours on different test cells and loading cycles, the model accurately reconstructed polarization curves and achieved 10x reduction in mean squared error (MSE) compared to a vanilla transformer. This proof-of-concept demonstrates that ML models can enable continuous performance monitoring for PEM electrolyzers and that the encoder captures meaningful latent representations of SoH, opening up opportunities to derive interpretable indicators in future work.

Reliable forecasting of renewable energy generation is a foundational requirement for grid stability energy trading battery scheduling and carbon aware operational planning Solar and wind resources are inherently intermittent their output fluctuates with cloud cover wind speed atmospheric turbulence seasonal patterns and local terrain The proliferation of IoT and edge devices spanning smart meters inverters anemometers pyranometers weather stations and grid interface sensors has created an unprecedented volume of real time operational data that conventional forecasting pipelines are ill equipped to exploit fully This review investigates how large language model LLM agents can enhance renewable energy forecasting by integrating heterogeneous sensor streams weather API data historical generation records grid constraints and contextual reasoning into unified decision support workflows We survey classical forecasting methods statistical time series models deep learning architectures physics hybrid approaches and emerging LLM agent frameworks for explanation uncertainty communication and operator guidance A six layer taxonomy is proposed covering data acquisition preprocessing feature engineering model inference uncertainty estimation and natural language reporting The review identifies twelve open challenges spanning real time deployment model drift under distribution shift uncertainty quantification hallucination control in LLM agents interoperability of edge hardware and integration with energy management systems The paper concludes by recommending a research agenda centred on open benchmarks physics informed LLM grounding and federated forecasting architectures