Greenhouse Gas

Nitrogen dioxide (NO2) is a common air pollutant, released into the atmosphere through the incomplete burning of fossil fuels, and associated with respiratory and cardiovascular diseases in humans. Ambient NO2 concentrations are regulated through air-quality limits assessed with a sparse network of fixed monitors. The revised EU Ambient Air Quality Directive (2024/2881) introduces a daily NO2 limit to be met from 2030. At present, neither the regulatory monitoring network nor existing coarse, annual-mean models can resolve NO2 concentrations at the spatio-temporal resolutions necessary to assess compliance. Here we map NO2 across Europe at hourly and 10m resolution with a machine-learning model that combines ground monitors with satellite, reanalysis, land-use, traffic and emission data and returns a calibrated predictive distribution at every location. Validated against held-out regulatory monitors and independent citizen-science campaigns, the maps resolve high-resolution spatiotemporal NO2 gradients for 110 metropolitan areas in Europe. We reconstruct the daily compliance statistic across those regions and find limit breaches in 91 EU air quality zones deemed compliant by the regulatory monitoring network, covering a population of approximately 135M. Beyond air quality zones and monitor locations, an estimated 9-9.4% (20M) of the population in mapped regions lives in areas where the daily NO2 limit is breached. The high-resolution maps offer a route to population-scale assessment of compliance with the 2030 limits.

Greenhouse gas emissions estimates can be derived using inverse methods by combining atmospheric concentration observations with chemical transport models. The latter traditionally use physics-driven simulators such as Lagrangian Particle Dispersion Models (LPDMs), which are expensive to run and do not scale well to modern satellites' high resolution data. Previously we developed a performant atmospheric transport emulator that approximates LPDM outputs ("footprints") over South America ~1,000X faster than the UK Met Office's LPDM. Expanding towards global emulation is not straightforward, as atmospheric transport is regionally heterogeneous. This paper evaluates spatial transferability capabilities of models across four world regions: South America, East Asia, South Asia, North Africa using both region-specific and multi-region models, and leave-one-region-out experiments. Regional differences are characterised in the context of input variable and output footprint distributions. This work builds intuition in cross-region generalisation and transfer learning, aiding regional performance towards efficient global emissions estimates.

The carbon footprint of any deployed Large Language Model (LLM) accumulates during inference, where repeated use of the model substantially exceeds the one-time cost of fine-tuning. Yet most efficiency interventions target either pre-training scale or post-hoc compression. We ask whether folding a calibrated, differentiable energy surrogate into the fine-tuning objective can produce inference behavior that gains task accuracy at zero or near-zero carbon cost, a break-even configuration. We propose a joint loss mechanism with a per-model carbon-emission parameter, a linear surrogate over parameter norm, FLOP proxy, and a memory proxy, fit from on-hardware energy profiling. We fine-tune three architecturally distinct families: Gemma-2 2B, Llama-3.1 8B, and Qwen-2.5 14B, and evaluate inference F1 and CO$_2$ emissions on three MMLU subjects: abstract algebra, philosophy, and formal logic. We discover from several outcomes that the carbon term behaves as either harmful interference or beneficial regularization depending on the task structure. We position calibrated carbon-aware fine-tuning as a lightweight, drop-in regularizer with a non-empty but model and task-dependent break-even region. This is an ongoing work, and we will release our codebase soon.

Nitrous oxide (N$_2$O) is the dominant ozone-depleting substance emitted in the 21st century, and the third largest contributor to anthropogenic greenhouse gases due to its high potency and long atmospheric lifetime, with more than 70% of N$_2$O emissions occurring as a result of agricultural processes. Current approaches to predicting N$_2$O flux emissions include process-based models such as DayCent and Cycles, as well as classical AI models, but the application of Physics-Informed Neural Networks (PINNs) to predicting N$_2$O flux emissions is largely underexplored. Our paper draws upon the mechanistic equations that underlie the DayCent family of process-based models to construct a rigorously derived, literature-traceable physics residual. We then build and train an MLP-based PINN on a multi-site agricultural dataset spanning four geographically distinct US agricultural sites. Across all tested values of the physics loss weighting hyperparameter $λ$, our PINN consistently and substantially outperformed uncalibrated Cycles simulation (R$^2=0.01$), with our MLP baseline achieving mean R$^2=0.411$ across ten random seeds. Physics constraints consistently degrade model performance in holdout validation, with marginal degradation at low $λ$ and significant degradation at high $λ$, but consistently improve model performance and reduce performance variability in leave-one-site-out validation. This suggests that physics constraints sacrifice in-distribution accuracy for out-of-distribution robustness, anchoring the model toward biogeochemically plausible behavior on unfamiliar soil conditions --- though cross-site generalization remains challenging, with negative R$^2$ across all seeds and $λ$ values on our geographically distinct held-out site.

Scope 3 greenhouse gas (GHG) emissions account for the majority of corporate carbon footprints, yet remain difficult to analyze at scale due to sparse disclosures, heterogeneous report document formats, and limited evidence traceability. Existing approaches typically rely on large language models to extract emissions information from ESG reports, but often lack explicit evidence grounding or depend on costly manual annotation and verification to ensure extraction reliability. To address these challenges, we propose Scope3Trace, an evidence-grounded information extraction framework designed to extract interpretable and traceable Scope 3 emissions information from real-world ESG and sustainability reports. The framework integrates a document information extraction pipeline that performs PDF collection and OCR parsing, LLM-assisted page localization and table reconstruction, and hybrid rule-LLM extraction of organization- and building-level emissions disclosures with evidence-grounded verification. Building upon this framework, we further contribute a dual-level, evidence-grounded, multimodal dataset comprising organization-level Scope 3 disclosures extracted from heterogeneous sustainability reports. Scope3Trace enables reliable extraction and transparent integration of heterogeneous sustainability disclosures, achieving high accuracy in extracting Scope 1-3 totals and category-level disclosures from sustainability reports.

Accurately estimating urban carbon emissions is critical for sustainable urban planning, yet many existing approaches remain difficult to apply consistently across cities due to data-source heterogeneity and the lack of fine-grained semantic-temporal context in remote sensing data. We propose CarbonCLIP, a task-oriented multimodal distillation framework that improves satellite-based carbon emission prediction by transferring contextual knowledge into a unified satellite representation through dual-branch contrastive learning. Unlike conventional methods that rely on static visual features, CarbonCLIP explicitly bridges the gap between top-down satellite views and ground-level human activities. Specifically, the spatial branch uses fine-grained textual descriptions automatically generated from street-view images by Large Multimodal Models (LMMs) to provide semantic priors reflecting building functions, infrastructure, and urban activities, while the temporal branch employs a month encoder to encode temporal priors associated with monthly emission variation. CarbonCLIP requires multimodal data only during the pretraining phase; during inference, it relies solely on satellite imagery, thereby supporting scalable deployment when ground-level data are unavailable at inference. Experiments on Beijing and Singapore demonstrate that CarbonCLIP outperforms baselines in both study cities. The results validate that our method effectively transfers multimodal knowledge into satellite representations, offering a robust solution for satellite-based urban carbon modeling.

Climate change, primarily driven by carbon dioxide (CO2) emissions, requires accurate forecasting tools to support effective mitigation policies and sustainable development strategies. Existing forecasting approaches typically rely on centralized data collection, which is often restricted by privacy regulations and the distributed nature of emission data across countries and industrial sectors. This paper proposes a novel federated hybrid forecasting framework that integrates ARIMA-based trend modeling, GARCH-based volatility modeling, LSTM-Attention temporal representation learning, and XGBoost prediction within a privacy-preserving federated learning environment. The proposed framework enables collaborative learning among distributed clients without requiring the exchange of raw data. Experimental evaluation across 14 clients demonstrates strong forecasting performance, achieving client R2 values between 0.50 and 0.97 with an average of 0.73, RMSE values ranging from 0.06 to 2.35 with an average of 1.21, and MAPE values between 1.5% and 11.3% with an average of 6.5%. The results indicate that the proposed framework provides an accurate, scalable, and regulation-compliant solution for collaborative carbon-emission forecasting.

Policy-oriented agent-based models are increasingly used to study regulatory interventions in complex adaptive socio-technical systems. Recent adaptive ABM frameworks distinguish between static and adaptive agents, fixed and adaptive policies, and alternative controller designs. However, most diagnostic workflows remain ex post: trajectories are analysed after simulation, but the resulting evidence is not systematically fed back into the policy controller. This paper proposes a lightweight machine-coached policy-revision layer for adaptive agent-based regulation. The layer represents policy decisions as defeasible rules with explicit conflicts and priorities, generates explanations for controller actions, and allows diagnostic failures to be translated into rule additions, removals, or priority changes. The contribution is not a new optimal controller and does not claim formal guarantees for unrestricted machine coaching. Instead, it provides a simulation-compatible operationalization of controller-level contestability: policy decisions can be explained, challenged, revised, and re-evaluated in held-out simulation runs. A stylized emissions-regulation ABM is used as the experimental component. A controlled simulation experiment focuses on an over-conservatism failure in the VPVA regime. The predefined coaching template adds a relaxation rule to the symbolic controller, reducing over-conservatism recurrence under held-out seeds while preserving violation, overshoot, and volatility guardrails. The paper argues that machine coaching is best understood as a controller-level extension of explainable adaptive ABM, complementary to causal, information-theoretic, and trajectory-based diagnostics.

The rapid expansion of AI globally has led to the proliferation of energy-intensive hyperscale data centres (DCs), making them as a structurally challenging component in power system planning and operation. Using a spatially explicit optimisation model of Europe across 21 AI growth scenarios, we systematically quantify additional demand, capacity requirements, emissions, and operational impacts of DCs. Results indicate that AI could drive 73-723 TWh of extra demand by 2050, risking cumulative emissions overshoots of 67-181 MtCO2 between 2030 and 2050. Our analysis indicates that after 2030, the geography of AI infrastructure will be shaped more by firm power and system flexibility than by the mere abundance of clean energy. In moderate scenarios, AI requires an additional of 200 hours of firm generation, which increases LCOE by 35 EUR/MWh in key hubs. We show that even under the pessimistic scenarios, existing infrastructure would require 70 GW additional capacity, while under managed growth pathways, this expansion could reach 226 GW. We further find DCs workload dynamics strongly shape energy dispatch, system flexibility, and emissions, while improved efficiency significantly reduces capacity needs, and system peaks. While our findings suggest that net-zero targets for 2050 may be achieved, critical emission risks may appear in the intermediate years, and the EU may compromise its carbon-neutral goals unless policies adapt to this accelerating digital transformation.

Machine learning-based predictive emissions monitoring systems offer a practical alternative to direct emissions measurement, but their deployment across gas turbine fleets is challenging when emissions labels are available for only a small subset of assets. In this work, a trust-aware probabilistic framework is proposed for fleet-level gas turbine NOx prediction under limited labelled supervision. The framework combines a multi-head recurrent prediction model with learned confidence estimation, ensemble-based uncertainty quantification, auxiliary feature prediction, feature-space distance analysis, and operating-range diagnostics. These signals are calibrated on labelled data to produce interpretable per-sample trust scores, providing indicators of prediction reliability on unlabelled turbines, supporting the identification of predictions that should be treated with greater caution during fleet-level deployment. Confidence-based filtering reduces MAE from 0.202 at full coverage to 0.070 for the highest-confidence 10% of predictions, demonstrating that confidence estimates are meaningfully related to prediction error. Unlabelled and out-of-distribution samples exhibit increased uncertainty and reduced confidence, indicating that the framework responds appropriately to distributional shift. The results show that the proposed trust framework provides actionable reliability information for emissions prediction on unlabelled turbines, supporting more transparent and trustworthy deployment of PEMS across industrial fleets.

Methane is a potent greenhouse gas that significantly contributes to global warming. However, accurately estimating global methane emissions and consumption remains challenging due to the complex interactions among environmental drivers that may vary across spatial and temporal scales. Prior data-driven methods often overlook the inherent spatiotemporal heterogeneity of ecosystems, failing to explicitly capture site-specific characteristics and cross-year evolutionary dynamics. To address these issues, we propose the Contrastive Hierarchical Adaptive Meta-network (CHAM-net), a novel framework that explicitly learns from historical context to capture site-specific dynamics. CHAM-net employs a hierarchical encoder-decoder architecture, in which the encoder captures site-specific characteristics from historical data and then dynamically conditions the decoder to generate the final prediction. Experimental results demonstrate that CHAM-net consistently outperforms all baseline methods on both simulation and observational datasets for methane emission and consumption, achieving nRMSE values as low as 0.43 and 0.88 with corresponding R2 scores up to 0.97 and 0.68 for emission prediction.

Accurate carbon emission monitoring is critical for climate policy and emerging regulatory mechanisms such as the EU Carbon Border Adjustment Mechanism, yet city-level high-frequency monitoring data remain extremely scarce, severely limiting data-hungry deep learning models. Time series generation is a natural remedy, but existing GAN and diffusion-based generators often provide limited explicit supervision for the domain structure of carbon emission data: they may match marginal distributional statistics while insufficiently preserving cross-variable correlations between CO$_2$ and co-emitted pollutants and meteorological factors, and tend to collapse the first-difference statistics of atmospheric measurements, producing sequences that are smooth on average but lack the realistic step-wise variability of the underlying signals. We propose TriHead-GAN, a Transformer-based adversarial framework whose triple-head discriminator jointly supervises three complementary aspects of the joint distribution: distributional authenticity via a Wasserstein critic, cross-variable dependency via leakage-free regression of the target variable, and step-wise temporal smoothness via adjacent-difference prediction. The generator combines global self-attention with local temporal convolution, per-step noise injection, and an anti-smoothing loss that matches first-difference statistics. Experiments on the self-collected Changsha Carbon dataset, two public carbon datasets (China, US), and the ETTh1 benchmark show that TriHead-GAN achieves favorable performance over mainstream baselines on the vast majority of settings, and that the resulting synthetic windows improve downstream forecasting accuracy in low-resource carbon monitoring scenarios.

The rapid growth of electric vehicles is shifting the main constraint on transport electrification from vehicle adoption to the deployment and operation of charging infrastructure. Charging-network design requires decisions across three interdependent layers: Planning, which determines where and how much infrastructure to build; Scheduling, which governs charging dispatch, pricing, and grid interaction; and Behavior, which captures how users choose stations, charging times, and charging durations. Existing studies have advanced each layer substantially, but the literature remains fragmented, and cross-layer interactions are often treated through simplifying assumptions. This survey develops a three-layer Planning-Scheduling-Behavior (PSB) framework to organize EV charging research according to decision horizon, actor objective, and coupling structure. We further identify a fidelity-tractability tradeoff, termed the PSB trilemma: each layer is computationally difficult in isolation, and realistic integration across layers generally requires reducing the fidelity of at least one layer. Reviewing the three pairwise-coupling literatures - Planning-Scheduling, Scheduling-Behavior, and Planning-Behavior - we show that the omitted third layer is typically fixed exogenously or represented by a static aggregate surrogate. These simplifications enable tractability but impose distinct costs: they can obscure long-term investment feedback, temporal grid and emissions dynamics, or heterogeneous user response and equity outcomes. Building on this diagnosis, we identify open challenges in emerging charging technologies, behavioral incentives, equity metrics, and city-scale learning-based methods that balance fidelity, interpretability, and policy relevance.

Global climate models are essential tools to simulate past and potential future pathways of climate change, as well as associated climate impacts. Shared Socioeconomic Pathways (SSPs) describe a range of future scenarios of global economic and demographic development. These SSPs are intrinsically linked to changes in climate forcings -- the external drivers, such as greenhouse gas and aerosol emissions, which change Earth's energy balance over time. These forcings act as boundary conditions in Earth System Models (ESM), providing insight into the potential climatic impacts of each SSP. Running an ESM, however, is extremely computationally expensive, conflicting with the need for large ensemble runs to provide robust estimates in the presence of internal variability and scenario uncertainty. Machine Learning emulators provide a promising avenue towards fast and cheap scenario generation, but until recently lacked uncertainty quantification and the ability to condition on external forcings. Here, we build upon recent work and extend it by training on multiple SSPs. We successfully generate scenarios of IPSL -- CM6A -- LR unseen during training and remain physically consistent with the underlying climate model, even under strong extrapolation scenarios. Our emulator is validated against MESMER -- M, a statistical emulator of land surface temperature. Our research demonstrates that our model, ArchesClimate -- SSP, does not simply imitate scenarios seen during training, but is actually capable of modeling the response of a climate state to diverse forcings. This is an important step towards reliable and rapid climate model scenario generation.

Open datasets and benchmarks for entity-level carbon-emission prediction remain fragmented across access, scale, granularity, and evaluation. We introduce GHGbench, an open dataset and benchmark for company- and building-level greenhouse-gas prediction. The company track contains 32,000+ company-year records from 12,000+ firms with Scope 1+2 and Scope 3 disclosures and financial/sectoral signals; the building track harmonises 491,591 building-year records from 13 open sources into a single schema across 26 metropolitan areas (10 U.S., 15 Australian, 1 Singaporean), with climate covariates and multimodal remote-sensing embeddings. GHGbench defines canonical splits with in-distribution and cross-region/city transfer as primary tasks and temporal hold-out plus short-horizon forecasting as supplementary appendix evidence; headline baselines span gradient-boosted trees, a tabular foundation model, MLP, FT-Transformer, and multimodal fusion, with an LLM panel as auxiliary, all evaluated under multi-seed paired-bootstrap tests. Three benchmark-level findings emerge: (i) building emissions are structurally harder than company emissions; (ii) the in-distribution to out-of-distribution gap dwarfs any within-model gap across both the company track and the building track, and a tabular foundation model is, to our knowledge, the first baseline to open a paired-bootstrap-significant gap over tuned trees on a multi-city building-emissions task; (iii) multimodal remote-sensing embeddings help precisely where tabular generalisation breaks. GHGbench also exposes catastrophic city transfer and the sector-factor lookup ceiling as systematic failure modes. Code and reconstruction recipes are available at GHGbench.

The growing deployment of large language models (LLMs) makes per-request routing essential for balancing response quality and computational cost across heterogeneous model pools. Current routing methods rarely consider sustainable energy use and CO2 emissions as optimization objectives, despite grid carbon intensity varying by time and region, and models differing significantly in energy consumption. To address this gap, we introduce Green-Aware Routing (GAR), a constrained multi-objective optimization framework that minimizes per-request CO2 emissions subject to explicit accuracy floors and p95-latency service-level objectives (SLOs). GAR employs adaptive constraint optimization through per-dataset floor tuning and incorporates lightweight estimators for correctness, tail latency, and carbon emissions, enabling real-time routing decisions without additional inference passes. We present GAR-PD, a practical online primal-dual routing algorithm for rolling carbon budgets, alongside heuristic variants that achieve high feasibility coverage while limiting accuracy degradation. Comprehensive experiments across standard NLP benchmarks with heterogeneous LLM pools (7B-70B) demonstrate that GAR achieves substantial carbon reductions while maintaining competitive accuracy and p95 latency guarantees, providing a practical, theoretically grounded approach to sustainable LLM inference.

Large language models (LLMs) impose rapidly growing energy demands, creating an emerging energy and carbon crisis driven by large-scale inference. Solar-powered, AI-enabled low Earth orbit (LEO) satellites have been proposed to mitigate terrestrial electricity consumption, but their lifecycle carbon footprint remains poorly understood due to launch emissions, satellite manufacturing, and radiation-hardened hardware requirements. This paper presents \textit{LLMSpace}, the first carbon modeling framework for LLM inference on AI-enabled LEO satellites. LLMSpace jointly models operational and embodied carbon, peripheral subsystems, radiation-hardened accelerators and memories, and LLM-specific workload characteristics such as prefill-decode behavior and token generation. Using realistic satellite and GPU configurations, LLMSpace reveals key trade-offs among carbon footprint, inference latency, hardware design, and operational lifetime for sustainable space-based LLM inference. Source code: https://github.com/UnchartedRLab/LLMSpace.

To understand complex system dynamics in dairy farming, it is essential to use modeling tools that capture farm heterogeneity, social interactions, and cumulative environmental impacts. This study proposes an agent-based modeling (ABM) framework to simulate nitrogen management and the adoption of low-emission fertilizer across 295 Irish dairy farms over a 15-year period. Using empirical data, the model represents farm communication through a social network, capturing peer influence and discussion group dynamics, where adoption probabilities are driven by social contagion, farm-scale characteristics, and policy interventions such as subsidies and carbon taxes. The framework estimates sectoral greenhouse gas emissions, cumulative abatement, and private-social cost trade-offs, using Monte Carlo simulation and sensitivity analysis to quantify uncertainty. The model shows strong agreement with observed adoption trajectories ($R^2 = 0.979$, RMSE = 0.0274) and is validated against empirical data using a Kolmogorov-Smirnov test (D = 0.2407, p < 0.001), indicating its ability to reproduce structural patterns in adoption behavior. Adoption dynamics are further characterized using a logistic diffusion model consistent with Rogers' innovation diffusion theory, capturing progression from early adoption to a saturation level of approximately 91%. By framing decarbonization as a socio-technical diffusion process rather than a purely economic optimization problem, this study provides an in silico policy laboratory for evaluating the robustness and diffusion speed of climate mitigation strategies prior to implementation.

Cement production is among the largest contributors to industrial air pollution, emitting ~3 Mt NOx/year. The industry-standard mitigation approach, selective non-catalytic reduction (SNCR), exhibits low NH3 utilization efficiency, resulting in operational inefficiencies and increased reagent costs. Here, we develop a data-driven framework for emission control using large-scale operational data from four cement plants worldwide. Benchmarking nine machine learning architectures, we observe that prediction error varies ~3-5x across plants due to variation in data richness. Incorporating short-term process history nearly triples NOx prediction accuracy, revealing that NOx formation carries substantial process memory, a timescale dependence that is absent in CO and CO2. Further, we develop models that forecast NOx overshoots as early as nine minutes, providing a buffer for operational adjustments. The developed framework controls NOx formation at the source, reducing NH3 consumption in downstream SNCR. Surrogate model projections estimate a ~34-64% reduction in NOx while preserving clinker quality, corresponding to a reduction of ~290 t NOx/year and ~58,000 USD/year in NH3 savings. This work establishes a generalizable framework for data-driven emission control, offering a pathway toward low-emission operation without structural modifications or additional hardware, with potential applicability to other hard-to-abate industries such as steel, glass, and lime.

Global greenhouse gas emissions estimates are essential for monitoring and mitigation planning. Existing emissions datasets provide critical foundations for understanding emissions patterns across sectors, geographies, and time scales. Through a structured assessment of recent emissions datasets, we identified opportunities to further increase the actionability of emissions data through more comprehensive source-level coverage, finer spatial and temporal resolution, and more frequent updates. Building on existing resources to address these opportunities, we present the Climate TRACE framework and resulting dataset, which is available on an open-access platform (climatetrace.org). The Climate TRACE framework synthesizes existing emissions data, prioritizing accuracy, coverage, and resolution, and fills remaining gaps using sector-specific estimation approaches. The resulting dataset is the first to provide global emissions estimates for individual sources (e.g., individual power plants) for most anthropogenic emitting sectors. The dataset spans January 1, 2021, to the present, with a two-month reporting lag and monthly updates. This dataset and open-access platform provides access to detailed emissions estimates for most subnational governments worldwide. By combining source-level spatial detail, monthly updates, and broad sectoral coverage, the dataset is designed to support analyses relevant to emissions monitoring and mitigation planning.

Carbon emissions significantly contribute to climate change, and carbon credits have emerged as a key tool for mitigating environmental damage and helping organizations manage their carbon footprint. Despite their growing importance across sectors, fully leveraging carbon credits remains challenging. This study explores engineering practices and fintech solutions to enhance carbon emission management. We first review the negative impacts of carbon emission non-disclosure, revealing its adverse effects on financial stability and market value. Organizations are encouraged to actively manage emissions and disclose relevant data to mitigate risks. Next, we analyze factors influencing carbon prices and review advanced prediction algorithms that optimize carbon credit purchasing strategies, reducing costs and improving efficiency. Additionally, we examine corporate carbon emission prediction models, which offer accurate performance assessments and aid in planning future carbon credit needs. By integrating carbon price and emission predictions, we propose research directions, including corporate carbon management cost forecasting. This study provides a foundation for future quantitative research on the financial and market impacts of carbon management practices and is the first systematic review focusing on computing solutions and engineering practices for carbon credits.