Methane

Achieving high combustion efficiency in flare stacks is crucial for adhering to regulatory standards and controlling the release of hydrocarbons into the environment. Traditional instruments like gas analyzers and hyperspectral cameras are expensive, fragile, and require frequent calibration, which makes them impractical for remote or budget constrained industrial sites. We propose an innovative solution that combines a lightweight vision-language encoder with a compact multi-layer perceptron to predict combustion efficiency directly from low-cost thermal video footage. The fully trained model is integrated into an easy-to-deploy graphical user interface. This interface overlays predicted combustion efficiency values on each video frame, displays real-time trends in combustion efficiency, shows the distribution of combustion efficiency across all frames in the video, and allows users to export CSV reports. Over a six-month period, the system achieved 99% uptime and required less than 15 minutes of maintenance per week.

Methane plume detection from satellite imagery is constrained by incomplete observations: public satellites provide complementary spatial, spectral, and atmospheric evidence, but real plume cases rarely contain fully paired multi-sensor measurements because of revisit schedules, cloud coverage, acquisition quality, and the transient nature of emissions. Most learning-based detectors rely on single-sensor inputs, especially Sentinel-2 (S2), leaving many reported plume cases unusable. We construct MethaneUnion, a temporal multi-sensor dataset built from Carbon Mapper plume reports and matched S2, Landsat 8/9 (L8/9), EMIT, and Sentinel-5P (S5P) observations. Built on MethaneUnion, MethaneFuse learns from heterogeneous satellite observations under partial sensor availability without requiring complete four-sensor measurements. MethaneUnion expands usable coverage from 3,211 valid S2-matched plume cases to 8,981 reported plume cases with multi-sensor observations. At the representative 480 m setting, MethaneFuse achieves 84.87 F1 and 93.62 AUROC, improving over the strongest baseline by 5.65 F1 and 8.30 AUROC points while reducing false positives by 8.19 points. Sensor-availability experiments show that MethaneFuse improves detection when S2 is available and transfers plume knowledge to L8/9, EMIT, and S5P when S2 is unavailable. These results demonstrate the value of learning from incomplete heterogeneous sensor observations for practical methane plume detection.

Dissolved gas analysis (DGA) is crucial for diagnosing early power transformer failures. Traditional DGA interpretation methods like Duval Triangle, IEC ratio, Roger ratio, Doernenburg ratio and Key Gas are inconsistent and vary in accuracy, especially for multiple fault conditions. We propose an Adaptive Multi-Fuzzy Logic (AMFL) model integrating multiple DGA methods with fuzzy logic and a dynamic weight adjustment mechanism. Unlike existing approaches with fixed weights, this system iteratively evaluates each method's diagnostic performance, identifies multiple fault types, and adjusts weights based on fault prediction accuracy. A feedback-based optimization recalibrates weights after each cycle to ensure optimal solution convergence. The model, implemented in MATLAB/Simulink, is validated against DGA datasets with known error conditions. Results show the AMFL model significantly improves diagnostic accuracy, especially in complex error scenarios, and enhances adaptability to new datasets. Comparative analysis demonstrates the proposed method outperforms traditional fixed weight multi-fuzzy systems in accuracy, consistency, and reliability of error detection. This work provides a robust, flexible diagnostic tool for transformer condition monitoring and supports more accurate asset management decisions.

Hydrogen infrastructure in enclosed environments, such as parking facilities for fuel cell vehicles, presents significant safety challenges due to hydrogen's low ignition energy and wide flammability range. Current monitoring systems are largely reactive, detecting leaks only after hazardous concentrations have formed. This study develops a computational framework for proactive sensor placement optimization by integrating computational fluid dynamics (CFD), genetic algorithm (GA) optimization, and a DeepSets neural surrogate. A CFD database of 180 scenarios was generated for a representative 50 m x 30 m x 3 m garage, covering multiple leak positions, rates (1-150 g/s), and ventilation conditions (ACH = 3-10 per hour). Sensor placement was optimized using a multi-objective GA and compared with uniform, random, and surrogate-assisted approaches. The GA achieved a detection rate of 96.1% within 60 s and reduced blind areas to 0.12%, corresponding to an approximately 5% improvement in composite fitness over a uniform baseline. The DeepSets surrogate reproduced near-optimal configurations with a fitness gap below 0.01 while reducing CFD evaluations by 89% and computational time by two orders of magnitude. Detection performance and spatial coverage remained comparable to the GA, demonstrating that surrogate-assisted optimization can retain solution quality while enabling rapid design iteration. Overall, the results show that CFD-informed optimization improves detection effectiveness and reduces sensor requirements compared to conventional layouts. The proposed framework supports scalable deployment and provides a foundation for integrating optimized sensor networks with digital twin systems for real-time monitoring and risk assessment.

Imaging spectrometers increasingly distribute source-resolved methane plume products in which the plume mask, integrated mass enhancement (IME), plume length, emission rate, and uncertainty are physically and algorithmically linked. Using 63 EMIT-derived Carbon Mapper plume records from 27 scenes, we show that these published scalar quantities do not uniquely constrain the plume boundary: substantially different yet plausible masks reproduce the same IME, plume length, and emission rate. Genetic-algorithm (GA) ensembles conditioned on the published IME and plume length make this equifinality explicit: the high-confidence core selected by nearly all target-consistent masks covers a median of 13% of the plausible footprint envelope, and ambiguity is largest for weak, low-overlap plumes. The diagnostics come from PlumeQuant, which recomputes IME, plume length, emission rate, and five-term uncertainty from distributed product components under stated conventions and evaluates four mask representations: the distributed reference mask, a transparent Carbon Mapper-informed analogue (CM-like), the GA ensemble, and optional expert edits. The CM-like mask is generated per plume without access to the reference mask or published quantities, with settings fixed once on a scene-disjoint 44-plume development split. It reproduced published IME with +0.72% median difference and emission rate with +0.16% (6.98% mean absolute), reached 0.843 median intersection-over-union against the reference masks, and matched the published uncertainty scale (median ratio 1.01). Holdout mean absolute errors were 7.6% (IME), 9.5% (length), and 6.1% (rate). These are product-level consistency diagnostics, not independent validation. They flag weak, offset, or ambiguous plumes for expert review.

The integrity of hydrogen infrastructure relies on reliable leak detection, performed almost exclusively via manual tracer gas sniffing in electrolyzer manufacturing. Although mandated by standards, the lack of spatial probe guidance instructions leaves detection reliability entirely to operator execution, further compromised by sensor signal delays. This study quantifies how sniffer trajectory kinematics affect detection reliability at small-scale pipes and fittings, a near-field regime largely neglected by macroscopic dispersion research. Using a robotically guided test bench to eliminate operator variability, static concentration fields and dynamic trajectory passes were acquired across representative geometries under standardized leak rates (5 vol% hydrogen in nitrogen) and varying scanning velocities. Results demonstrate that scanning velocity and spatial probe orientation strongly dictate detectability. Conventional linear trajectories frequently miss leaks under dynamic conditions, causing severe false negatives. Conversely, geometry-specific routing, such as circumferential plunging paths around sealing points, maintains a high safety margin. From these observations, geometry-specific routing rules and a reduction-factor model for dynamic signal loss are derived. The findings reveal that current standard operating procedures pose a tangible safety risk. To operationalize these rules, a proof-of-concept software pipeline is presented, generating validated trajectories directly from 3D models for visualization in assistance systems.

Inspired by advances in natural language processing and computer vision, "time-series foundation models" (TSFMs) have recently been introduced with the promise of strong generalization across diverse time-series tasks, including forecasting, classification, and anomaly detection, as well as across domains such as healthcare, climate science, and manufacturing. However, their utility for gas-sensing data remains largely unexplored. To address this gap, this paper systematically evaluates recent TSFMs on electronic nose (E-Nose) data. In particular, we investigate whether embeddings produced by representative TSFMs, including Chronos-2 and MOMENT, provide effective representations for gas identification and concentration prediction. Specifically, we show that fine-tuning is necessary to achieve satisfactory performance on E-Nose data, and fusing TSFM embeddings with representations learned by specialized predictive models can further improve the performance, suggesting both the potential and limitations of current TSFMs for gas-sensing applications.

Efficient detection of methane plumes is crucial for understanding and mitigating global warming, as accurately identifying and segmenting them in earth observation imagery remain essential for large-scale monitoring. In this work, we propose a multimodal deep learning model that integrates a feature-guided methane enhancement (FGME) mechanism which injects physically meaningful methane cues into transformer-based RGB representations at multiple semantic scales. Our method is evaluated on the MPDataset, where it outperforms the state-of-the-art with improvements of +0.92 in MIoU, +0.87 in MPrecision and +1.01 in Recall. Notably, these gains are obtained with a substantially lower computational cost than other high-performing architectures, resulting in a favorable accuracy-efficiency trade-off for large-scale methane monitoring. These results highlight the potential of efficient multimodal fusion strategies for accurate and scalable methane plume segmentation in real-world remote sensing applications.

Multi-fuel compression-ignition engines offer fuel flexibility but introduce uncertain, time-varying fuel reactivity, represented by cetane number (CN), which complicates cycle-to-cycle combustion-phasing control. This work formulates CA50 regulation under latent CN variation as a partially observable sequential decision problem and systematically evaluates controllers with increasing temporal and representational capacity, including LinUCB, history-augmented contextual bandits, observation-only DDPG, recurrent DDPG, and a proposed GRU-guided RL framework. A Gaussian-process surrogate trained on experimental multi-fuel engine data provides a controlled and reproducible evaluation environment. Results show that myopic and fixed-history bandit methods degrade under CN variation, observation-only RL suffers from latent-state aliasing, and generic recurrence is insufficient when CN evolves rapidly. The proposed framework learns a compact GRU-based representation of fuel reactivity from combustion history and conditions both actor and critic on this estimated signal rather than oracle CN. By training the policy on the same imperfect fuel-reactivity information available at deployment, the controller avoids train-deploy inconsistency in conventional online estimate-then-control pipelines. Across unseen CN trajectories, the policy achieves stable CA50 regulation with mean absolute tracking error below 0.25° CA at the training setpoint, while producing smooth, physically consistent SOI and glow-plug-power actuation. These results show that combustion control under latent, continuously evolving fuel dynamics requires more than standalone estimation or generic recurrence. By aligning fuel-reactivity inference with control policy learning, the proposed framework enables reactivity-aware decision-making using the same estimated state available during deployment.

Methane is a potent greenhouse gas, and detecting leaks early via hyperspectral satellite imagery can help climate change mitigation efforts. Meanwhile, many existing hyperspectral missions only capture areas manually targeted by operators, thus missing potential events of interest. To overcome slow downlink rates cost-effectively, onboard detection is a viable solution. However, traditional methane detection methods are too computationally demanding for resource-limited onboard hardware. This work accelerates methane detection by focusing on efficient, low-power algorithms. In particular, we test fast target detection ACE and CEM methods that have not been previously used for methane detection and propose Mag1c-SAS -- a significantly faster variant of the current state-of-the-art Mag1c algorithm. To explore their detection potential, we integrate them with a machine learning model based on U-Net and LinkNet. We evaluate our methods on the STARCOP dataset and a novel EMIT-MSeg dataset, which we introduce and open-source alongside a high-quality annotation strategy. The proposed Mag1c-SAS approach proves highly effective by operating ~80x faster than the original Mag1c approach, providing a visually similar, but noisier result. When additionally paired with the lightweight LinkNet approach, it effectively reduces noise, achieving AUPRC score improvements of over 30 pp on EMIT-MSeg compared to the baseline Mag1c approach, and an F1 score on STARCOP ~4 pp higher. We evaluate two novel band selection strategies and confirm the system's onboard viability through hardware profiling, demonstrating marginal power consumption and efficient CPU/RAM utilization. We release the final system in a user-friendly and lightweight PyPI library at: https://pypi.org/project/onboard-methane-detection/, alongside all experimental code, models, and data at: https://github.com/zaitra/methane-filters-benchmark.

Turbulent combustion simulations are crucial for many scientific and engineering systems. However, the high cost to fully resolve the complex multiscale and multiphysics behavior makes direct simulation typically infeasible. The equivalent reactor network (ERN) approach attempts to improve computational efficiency by replacing a multidimensional turbulent simulation with a series of much cheaper 0-D and 1-D chemical reactors, providing a surrogate model that retains detailed chemistry at the cost of simplified flow physics. However, their development remains a challenge, often requiring either expert analysis, or automated approaches that sacrifice accuracy. In this work, we develop an automated machine-learning-assisted framework for constructing ERNs of the Sandia-D turbulent methane/air flame. Principal component analysis is first used to reduce high-dimensional thermochemical computational fluid dynamics (CFD) data to a low-dimensional latent space, where k-means clustering identifies physically interpretable flame regions used to initialize a reactor-network graph. This initialization is then refined using finite-difference gradient descent wrapped around non-differentiable Cantera reactor simulations. Across 30 RANS simulations spanning a range of pilot temperatures and inlet methane compositions, the optimized 7-reactor ERN achieves a maximum-temperature $R^2$ score of 0.7945 while preserving a $\sim6000\times$ speedup over the CFD solver. Outlet CO prediction remains more challenging, with a final $R^2$ score of $-0.4183$, but improves substantially from the unoptimized clustering initialization. These results show that unsupervised thermochemical feature extraction can provide effective physics-informed initializations for ERN construction, while gradient-based refinement can significantly improve predictive accuracy without manual reactor-network design.

Methane is a major driver of near-term climate change, and rapidly identifying its emission sources is a critical climate intervention. Spaceborne hyperspectral imagery is the primary tool for this task, but the volume of data produced by each sensor makes ground-based detection impractical and necessitates onboard detection. Classical methods incur prohibitive computational cost on onboard hardware, while deep learning models are fast but fall short on detection quality. We propose FLAME, a physics-guided neural operator that builds the physics of methane absorption directly into its architecture. On the methane detection benchmark, FLAME achieves the highest detection accuracy among all evaluated methods, reduces the pixel-level false positive rate by nearly $3\times$ over the strongest neural baseline, uses the fewest parameters among learned baselines, and runs within the latency budget of onboard satellite hardware.

Continuous and global detection of large methane emissions is a crucial step for global warming mitigation. Satellite observations, such as from S5P/TROPOMI, combined with plume detection algorithms, can play a key role in this effort. However, not all TROPOMI plume detections that look like methane emission plumes are the result of actual emissions. A significant part of the plume-like features in the data are retrieval artifacts. Such artifacts could be the result of variations in elevation or albedo gradients, high concentrations of aerosols, coastal lines, water bodies, etc. Previous work approached the problem of plume-artifact classification by means of a Support Vector Machine Classifier (SVC), trained on an extensive set of observation-based scalar features designed by domain experts. However, such an approach limits the information scope received by the algorithm to what is deemed to be important by the experts, breaks the spatial relationship between pixels, and loses information during the process of statistical aggregation. In this study, we compare feature-based (SVC, Random Forest, XGBoost) and image-based (ResNet-18, ResNet-34) models for methane plume-artifact classification under balanced and imbalanced evaluation settings. To interpret the results, we apply SHAP-based explainability to both model families. Our findings provide practical guidance for model selection in operational methane-screening workflows such as the CAMS Methane Hotspot Explorer.

Automated detection and masking of individual methane plumes from satellite imagery is important for operational emission attribution and quantification. We present a machine learning framework for plume detection from MethaneSAT retrieved column-averaged dry-air mole fractions of methane. We address two core challenges: the scarcity of labeled MethaneSAT data and the need for inference reliability across diverse atmospheric and surface conditions. We first demonstrate that Mask R-CNN with a ResNet-50 backbone outperforms U-Net semantic segmentation on both MethaneAIR (an airborne version of MethaneSAT) and MethaneSAT data, with pixel-level F1 score gains of 10.49 and 5.48 respectively. To address MethaneSAT data scarcity, we evaluate three cross-sensor transfer strategies leveraging MethaneAIR flights and synthetic plumes. Mask R-CNN with ResNet-50 fine-tuned from MethaneAIR pre-trained weights is the most effective strategy, achieving instance-level precision of 0.60 and a near-perfect recall of 0.98 at the baseline operating point. A physics-informed post-processing pipeline converts detections into two operationally distinct modes. The first is a high-sensitivity mode that applies morphological filtering and proximity-based merging for comprehensive emission screening, achieving precision of 0.71 and recall of 0.94. The second is a high-precision mode that additionally applies a distribution-based classifier for confident source attribution, achieving precision of 0.92 and recall of 0.70. Manual review of detections classified as false positives against our wavelet-based ground truth labels reveals that a meaningful fraction of cases correspond to real methane enhancements excluded by conservative labeling criteria, indicating that precision values reported are lower bounds on true detection performance... Our data and code are available at: https://doi.org/10.7910/DVN/FR959H

This work presents a physics-guided machine-learning framework for carbon monoxide concentration inference from experimentally measured resistance transients of a mixed-phase SnO-SnO$_2$ material gas sensor exhibiting temperature-dependent p-n switching behavior. Cycle-level transient responses are represented through physically interpretable descriptors and complemented by compact fast Fourier transform (FFT) and discrete wavelet transform (DWT)-based summaries. Using leakage-aware grouped cross-validation, we study both multi-class concentration classification and continuous concentration regression for the p-type and n-type sensing regimes separately. Across both regimes, fused features provide the strongest overall performance, while the physics-guided descriptor block remains highly competitive, indicating that the dominant concentration information is already encoded in physically meaningful transient dynamics. The p-type branch shows the best concentration-class discrimination, with the fused Random Forest classifier reaching approximately $96.5\%$ accuracy, whereas the n-type branch yields the best quantitative concentration estimation, with the fused Random Forest regressor achieving an MAE$\approx 1.48$ ppm and an R$^2$ $\approx 0.992$. These results reveal a clear dual-regime behavior: p-type sensing is particularly favorable for classification, whereas n-type sensing is more favorable for high-fidelity regression. More broadly, the study demonstrates that leakage-aware, cycle-level, physics-guided machine learning can extend conventional gas-sensing analysis beyond single-response metrics while preserving physical interpretability

Efficient Gas Source Localization (GSL) in real-world settings is crucial, especially in emergency scenarios. Mobile robots equipped with low-cost, in-situ gas sensors offer a safer alternative to human inspection in hazardous environments. Probabilistic algorithms enhance GSL efficiency with scattered gas measurements by comparing gas concentration measurements gathered by robots to physical dispersion models. However, accurately deriving gas concentrations from data acquired with low-cost sensors is challenging due to the nonlinear sensor response, environmental dependencies (e.g., humidity, temperature, and other gas influences), and robot motion. Mitigating these disturbance factors requires frequent sensor calibration in controlled environments, which is often impractical for real-world deployments. To overcome these issues, we propose a novel feature extraction algorithm that leverages the relative ranking of gas measurements within the dynamically accumulated dataset. By comparing the rank differences between gathered and modeled values, we estimate the probabilistic distribution of source locations across the entire environment. We validate our approach in high-fidelity simulations and physical experiments, demonstrating consistent localization accuracy with uncalibrated gas sensors. Compared to existing methods, our technique eliminates the need for gas sensor calibration, making it well-suited for real-world applications.

The current catalyst discovery and development pipeline for energy-intensive applications like methane conversion remains bottlenecked by expensive trial-and-error experimentation, irreproducible chemical intuition, and a lack of frameworks linking complex catalytic design spaces to performance. This work presents an interpretable machine learning framework that integrates SHAP-based feature importance analysis (Explainable AI) with tree-based ensembles (Random Forest and Bayesian-optimized CatBoost) to characterize Fe-zeolite and oxide-supported catalysts for the partial oxidation of methane (POM). Despite limited data, the framework decodes complex structure-performance relationships by identifying and ranking thermodynamic, structural, and geometric microdescriptors that influence the electronic band gap and govern macroscale performance metrics such as selectivity, activity, and stability. This work explicitly demonstrates that thermodynamic lattice stability and geometric factors are the primary drivers of electronic band gap (a critical proxy for redox reactivity) rather than bulk stoichiometry. Non-linear models achieve an R2 of 0.61 - 0.77, significantly outperforming traditional linear baselines (R2 = 0.32). This workflow provides both a light-weight generalizable methodology and a prioritized list of physical features for accelerated catalyst screening - and these features can subsequently be integrated into microkinetic and reaction engineering models to create digital twins of complex reactor systems and to enable predictive optimization in autonomous R&D laboratories.

Future imaging spectrometers will increase data volumes by orders of magnitude, requiring automated detection of trace gas point sources. We present a fully automated framework that combines machine learning-based morphological analysis with physics-based spectroscopic fitting to detect plumes without human participation. Applied to EMIT imaging spectrometer data, the system operates in two modes: "daily digest" that runs automatically on all downlinked data, flagging the largest events for immediate response, and a retrospective analysis that identifies plumes missed by prior human review. The daily digest demonstrates that a significant fraction of the largest plumes can be detected automatically with negligible false positives, while retrospective analysis suggests at least 25% of plumes may have been overlooked. In addition to the previously observed methane point sources, we extend detection to three understudied trace gases: NH3, NO2 and the first observations of carbon monoxide (CO) plume in EMIT imagery.

Laser absorption spectroscopy (LAS) is a well-established technique for non-intrusive measurement of gas species in combustion and atmospheric environments, but conventional methods struggle with multi-species mixtures under dynamic or interference-laden conditions. Overlapping spectral features, noise, and incomplete reference data limit reliability when unknown or weakly absorbing species are present. This dissertation develops diagnostics combining LAS with machine learning (ML) to address these limitations. Deep denoising autoencoders (DDAEs) are applied to shock-tube measurements during high-speed hydrocarbon pyrolysis, improving signal fidelity and detection limits for trace species. A structured unsupervised framework, HT-SIMNet, then mitigates interference from unknown species without full calibration data, using spectral augmentation and a Noise2Noise-inspired scheme to isolate species in reactive systems. Where reference spectra are unavailable, UnblindMix, an autoencoder-based blind source separation method, reconstructs concentrations and spectral signatures directly from mixture data, validated on mixtures of up to eight components. To recover weakly absorbing species masked by broader absorbers, a feature-engineering method based on first derivatives and convolutions selectively highlights minor species. Finally, VOC-certifire combines randomized smoothing with Voigt-based spectral perturbation to provide certifiable classification of volatile organic compounds under varying conditions. All techniques are experimentally validated and benchmarked. The integration of spectroscopic hardware with ML offers a path toward real-time, interference-resilient, reference-free gas detection for combustion science, environmental monitoring, and industrial safety.

Gas leaks pose severe risks to human health and industrial safety. However, accurate and timely monitoring of gas leaks remains a major challenge. Existing vision-based methods using infrared (IR) imagery are limited by the inherently blurry and non-rigid nature of leak plumes, which reduces detection reliability and precision. To overcome these limitations, this paper proposes a Joint Vision-Language Gas leak Segmentation (JVLGS) framework that integrates the complementary strengths of visual and textual modalities to enhance gas leak segmentation. Recognizing that gas leaks are sporadic and many video frames contain no leakage, JVLGS incorporates an adaptive postprocessing module to effectively suppress false positives caused by noise and non-target objects-a common limitation of existing approaches. Extensive experiments across diverse industrial scenarios demonstrate that JVLGS significantly outperforms state-of-the-art gas leak segmentation methods. Furthermore, it achieves consistently strong performance under both supervised and few-shot learning settings, whereas competing methods typically perform well in only one setting or underperform in both.